Brazil’s Stephan de Freitas Barcha and Chevaux Primavera Imperio Egipcio earned the individual gold in a hard-fought final.
The three team qualifying spots for the Paris 2024 Olympic Games went to the USA, Canada and fourth-placed Mexico.
There were some surprises as the USA is relegated to fifth, with Brazil and Colombia leading the field going into the Team Final tomorrow.
Canada's Beth Underhill and Nikka Vd Bisschop place 6th with two spectacular clear efforts in the rich €350,000 event.
The dutch rider piloted Uricas vd Kattevennen to the win, while Canada's Beth Underhill places 15th with Nikka vd Bisschop.
The British rider managed to oust the Germans from the top of the podium on home turf; Beth Underhill will ride with the Rome Gladiators.
Last year's winner, Canada's Beth Underhill, places 7th riding Nikka VD Bisschop after an exciting 14-horse jump-off at the French venue.
The German claimed the Rolex title with the brilliant mare DSP Chakaria in a tense 13-way jump-off at Piazza di Siena.
The 2nd of three Nations Cups to be held in North America took place in San Juan Capistrano and was won by Team USA, who lead the standings.
Eventers, show jumpers and dressage athletes all have impressive results in competitions in the US, the UK and Spain.